b-D-Glucopyranosyl azide,2,3,4,6-tetraacetate
- 中文别名：1-叠氮-1-脱氧-β-D-吡喃葡萄糖苷四乙酸
- 中文释义：1-叠氮-1-脱氧-β-D-吡喃葡萄糖苷四乙酸酯;1-叠氮-1-脱氧-β-D-吡喃葡萄糖苷四乙酸
- 英文别名：1-AZIDO-2,3,4,6-TETRA-O-ACETYL-β-D-GLUCOSE;
2,3,4,6-Tetra-O-acetyl-D-glucopyranosyl azide;
acetic acid 3,4,5-triacetoxy-6-azido-tetrahydro-pyran-2-ylmethyl ester;
1-AZIDO-2,3,4,6-TETRA-O-ACETYL-SS-D-GLUCOSE;
2,3,4,6-Tetra-O-acetyl-b-D-glucopyranosylazide;
2,3,4,6-TETRA-O-ACETYL-SS-D-GLUCOPYRANOSYL AZIDE;
1-AZIDO-2,3,4,6-TETRA-O-ACETYL-B-D-GLUCOSE;
1-Azido-2,3,4,6-tetra-O-acetyl-D-glucose
- CAS No.：13992-25-1
- 分子式：C14H19N3O9
- 分子量：373.32
- 精确分子量：373.11200
- PSA：164.18000
- MDL：MFCD00181721
- InChI：InChI=1/C14H20N3O9/c1-6(18)22-5-10-11(23-7(2)19)12(24-8(3)20)13(25-9(4)21)14(26-10)16-17-15/h10-15H,5H2,1-4H3/q+1
- 分子结构式：
物化性质
- 外观与性状：
- 米色固体
- 熔点：
- 127-131 °C(lit.)
- 其它信息：
1．性状：不可用
2．密度（g/mL,25/4℃）：不可用
3．相对蒸汽密度（g/mL,空气=1）：不可用
4．熔点（ºC）：127-131
5．沸点（ºC,常压）：不可用
6．沸点（ºC,5.2kPa）：不可用
7．折射率：不可用
8．闪点（ºC）：不可用
9．比旋光度（º）：不可用
10．自燃点或引燃温度（ºC）：不可用
11．蒸气压（kPa,25ºC）：不可用
12．饱和蒸气压（kPa,60ºC）：不可用
13．燃烧热（KJ/mol）：不可用
14．临界温度（ºC）：不可用
15．临界压力（KPa）：不可用
16．油水（辛醇/水）分配系数的对数值：不可用
17．爆炸上限（%,V/V）：不可用
18．爆炸下限（%,V/V）：不可用
19．溶解性：不可用
安全信息
- 外观与性状：
- 米色固体
- 熔点：
- 127-131 °C(lit.)
- 其它信息：
1．性状：不可用
2．密度（g/mL,25/4℃）：不可用
3．相对蒸汽密度（g/mL,空气=1）：不可用
4．熔点（ºC）：127-131
5．沸点（ºC,常压）：不可用
6．沸点（ºC,5.2kPa）：不可用
7．折射率：不可用
8．闪点（ºC）：不可用
9．比旋光度（º）：不可用
10．自燃点或引燃温度（ºC）：不可用
11．蒸气压（kPa,25ºC）：不可用
12．饱和蒸气压（kPa,60ºC）：不可用
13．燃烧热（KJ/mol）：不可用
14．临界温度（ºC）：不可用
15．临界压力（KPa）：不可用
16．油水（辛醇/水）分配系数的对数值：不可用
17．爆炸上限（%,V/V）：不可用
18．爆炸下限（%,V/V）：不可用
19．溶解性：不可用
毒理性
- 毒理学数据：
急性毒性：不可用。
- 生态数据：
1、其它有害作用：该物质对环境可能有危害，对水体应给予特别注意。
MSDS
| Name: | 2 3 4 6-Tetra-o-acetyl-betha-d-glucopyranosyl azide 98% Material Safety Data Sheet |
| Synonym: | |
| CAS: | 13992-25-1 |
Section 1 - Chemical Product MSDS Name:2 3 4 6-Tetra-o-acetyl-betha-d-glucopyranosyl azide 98% Material Safety Data Sheet
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | content | EINECS# |
| 13992-25-1 | 2,3,4,6-TETRA-O-ACETYL-BETHA-D-GLUCOPY | 98% | unlisted |
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.Light sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 13992-25-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: beige
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 129 - 130 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C14H19N3O9
Molecular Weight: 373.32
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing materials.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13992-25-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,3,4,6-TETRA-O-ACETYL-BETHA-D-GLUCOPYRANOSYL AZIDE - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 13992-25-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13992-25-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13992-25-1 is not listed on the TSCA inventory.
It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
N/A
分子结构与计算化学数据
分子结构数据
1、摩尔折射率：无可用的
2、摩尔体积（cm3/mol）：无可用的
3、等张比容（90.2K）：无可用的
4、表面张力（dyne/cm）：无可用的
5、介电常数：无可用的
6、极化率（10-24cm3）：无可用的
7、单一同位素质量：373.112129 Da
8、标称质量：373 Da
9、平均质量：373.3154 Da
