9-Tetradecen-1-ol,1-acetate, (9Z)-
- 中文别名：醋酸(Z)-9-十四烯酯
- 中文释义：顺-9-十四碳烯乙酸酯;醋酸(Z)-9-十四烯酯
- 英文别名：[(Z)-tetradec-9-enyl] acetate;
cis-9-Tetradecenyl acetate;
9-tetradecenyl Acetate;
EINECS 240-780-1
- CAS No.：16725-53-4
- 分子式：C16H30O2
- 分子量：254.41
- 精确分子量：254.22500
- PSA：26.30000
- InChI：The Key: XXPBOEBNDHAAQH-SREVYHEPSA-N
- 分子结构式：
物化性质
- 外观与性状：
- 无色至淡黄色液体
- 密度：
- 0.878 g/cm3
- 熔点：
- 41987ºC
- 沸点：
- 135ºC(0.5 mmHg)
- 闪点：
- 98.5ºC
- 折射率：
- 1.4455-1.4475
- 蒸汽压：
- 0.000136mmHg at 25°C
- 其它信息：
1.性状：未确定
2.密度（g/mL,25/4℃）：0.87 醋酸(Z)-9-十四烯酯 安全信息
- 海关代码：
- 2915390090
- 安全说明：
- S24/25
- 安全标志：
- S24/25:防止皮肤和眼睛接触。
安全信息
- 外观与性状：
- 无色至淡黄色液体
- 密度：
- 0.878 g/cm3
- 熔点：
- 41987ºC
- 沸点：
- 135ºC(0.5 mmHg)
- 闪点：
- 98.5ºC
- 折射率：
- 1.4455-1.4475
- 蒸汽压：
- 0.000136mmHg at 25°C
- 其它信息：
1.性状：未确定
2.密度（g/mL,25/4℃）：0.87
醋酸(Z)-9-十四烯酯 安全信息
- 海关代码：
- 2915390090
- 安全说明：
- S24/25
- 安全标志：
- S24/25:防止皮肤和眼睛接触。
MSDS
| Name: | Cis-9-Tetradecenyl Acetate 95% Material Safety Data Sheet |
| Synonym: | Myristoleyl acetate; Z-9-TDA |
| CAS: | 16725-53-4 |
Section 1 - Chemical Product MSDS Name:Cis-9-Tetradecenyl Acetate 95% Material Safety Data Sheet
Synonym:Myristoleyl acetate; Z-9-TDA
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | content | EINECS# |
| 16725-53-4 | cis-9-Tetradecenyl acetate | 95% | 240-780-1 |
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If inhaled, remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 16725-53-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 135 deg C @0.5mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 0.870
Molecular Formula: C16H30O2
Molecular Weight: 254
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 16725-53-4: XB9130000 LD50/LC50:
CAS# 16725-53-4: Oral, rat: LD50 = >5000 mg/kg.
Carcinogenicity:
cis-9-Tetradecenyl acetate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 16725-53-4: No information available.
Canada
CAS# 16725-53-4 is listed on Canada's NDSL List.
CAS# 16725-53-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16725-53-4 is listed on the TSCA inventory.
SECTION 16 - ADDITIONAL INFORMATION
N/A
海关数据
中国海关编码：2915390090
- 概述：
- 2915390090. 其他乙酸酯. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%
- 申报要素：
- 品名, 成分含量, 用途
- 监管条件：
- A.入境货物通关单B.出境货物通关单
- 检验检疫：
- R.进口食品卫生监督检验S.出口食品卫生监督检验M.进口商品检验N.出口商品检验
- 摘要/Summary：
- 2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%
分子结构与计算化学数据
分子结构数据
1、 摩尔折射率：78.00
2、 摩尔体积（m3/mol）：289.7
3、 等张比容（90.2K）：680.6
4、 表面张力（dyne/cm）：30.4
5、 极化率（10-24cm3）：30.92
计算化学数据
1.疏水参数计算参考值（XlogP）:5.9
2.氢键供体数量:0
3.氢键受体数量:2
4.可旋转化学键数量:13
5.互变异构体数量:无
6.拓扑分子极性表面积26.3
7.重原子数量:18
8.表面电荷:0
9.复杂度:209
10.同位素原子数量:0
11.确定原子立构中心数量:0
12.不确定原子立构中心数量:0
13.确定化学键立构中心数量:1
14.不确定化学键立构中心数量:0
15.共价键单元数量:1
