hydrazine monohydrobromide

物化性质

外观与性状：

白色晶体

熔点：

87-92 °C(lit.)

沸点：

190°C

闪点：

190°C

蒸汽压：

20.7mmHg at 25°C

存储条件/存储方法：

常温密闭，阴凉通风干燥

稳定性相关：

常温常压下稳定

避免的物料 水分/潮湿 氧化物

其它信息：

1. 性状：无色晶体

2. 密度（g/mL,25/4℃）：未确定

3. 相对蒸汽密度（g/mL,空气=1）：2.3

4. 熔点（ºC）：87-92

5. 沸点（ºC,常压）：190

6. 沸点（ºC,5.2kPa）：未确定

7. 折射率：未确定

8. 闪点（ºC）：未确定

9. 比旋光度（º）：未确定

10. 自燃点或引燃温度（ºC）：未确定

11. 蒸气压（kPa,25ºC）：未确定

12. 饱和蒸气压（kPa,60ºC）：未确定

13. 燃烧热（KJ/mol）：未确定

14. 临界温度（ºC）：未确定

15. 临界压力（KPa）：未确定

16. 油水（辛醇/水）分配系数的对数值：未确定

17. 爆炸上限（%,V/V）：未确定

18. 爆炸下限（%,V/V）：未确定

19. 溶解性：溶于水和低级醇，不溶于有机溶剂

安全信息

外观与性状：

白色晶体

熔点：

87-92 °C(lit.)

沸点：

190°C

闪点：

190°C

蒸汽压：

20.7mmHg at 25°C

存储条件/存储方法：

常温密闭，阴凉通风干燥

稳定性相关：

常温常压下稳定

避免的物料 水分/潮湿 氧化物

其它信息：

1. 性状：无色晶体

2. 密度（g/mL,25/4℃）：未确定

3. 相对蒸汽密度（g/mL,空气=1）：2.3

4. 熔点（ºC）：87-92

5. 沸点（ºC,常压）：190

6. 沸点（ºC,5.2kPa）：未确定

7. 折射率：未确定

8. 闪点（ºC）：未确定

9. 比旋光度（º）：未确定

10. 自燃点或引燃温度（ºC）：未确定

11. 蒸气压（kPa,25ºC）：未确定

12. 饱和蒸气压（kPa,60ºC）：未确定

13. 燃烧热（KJ/mol）：未确定

14. 临界温度（ºC）：未确定

15. 临界压力（KPa）：未确定

16. 油水（辛醇/水）分配系数的对数值：未确定

17. 爆炸上限（%,V/V）：未确定

18. 爆炸下限（%,V/V）：未确定

19. 溶解性：溶于水和低级醇，不溶于有机溶剂

毒理性

毒理学数据：

1、急性毒性：主要的刺激性影响：

在皮肤上面：在皮肤和粘膜上造成腐蚀性影响，刺激皮肤和粘膜；

在眼睛上面：强烈的腐蚀性影响，刺激的影响；没有已知的敏化影响。

生态数据：

对水体是极其有害的，即使小量产品也不能接触地下水，水道或污水系统, 若无政府许可，勿将材料排入周围环境

MSDS

Section I.Chemical Product and Company Identification
Chemical Name Hydrazine Monohydrobromide
Portland OR
SynonymHydrazine, hydrobromide (1:1) (CA INDEX NAME);
Hydrazinium Monobromide
H4N2•HBr
Chemical Formula
CAS Number13775-80-9
Section II.Composition and Information on Ingredients
Toxicology Data
Chemical NameCAS Number Percent (%)TLV/PEL
This chemical is classified as a Not available.
Hydrazine Monohydrobromide13775-80-9Min. 98.0 (T)
possible carcinogen. There is
no acceptable exposure limit for
a carcinogen.
This compound is classified as
a possible mutagen. There is
no acceptable exposure limit for
a mutagen.
Section III. Hazards Identification
Toxic if ingested or inhaled. Avoid prolonged contact with this material. Overexposure may result in serious illness or death.
Acute Health Effects
Corrosive to skin, eyes, and respiratory system. Liquid or spray mist may produce tissue damage, particularly in mucous
membranes of the eyes, mouth and respiratory tract. Skin contact may produce burns. Eye contact can result in corneal
damage or blindness. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking, or shortness of breath. Corrosive materials may cause serious injury if ingested.
Skin contact may result in sensitization. Always cover all exposed skin with an impermeable layer and use proper eye
protection. A OSHA/MSHA approved dust and vapor respirator is required when working with this material.
Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
CARCINOGENIC EFFECTS : Not available.
Chronic Health Effects
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local
skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung
damage. Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in
one or many human organs.
Section IV.First Aid Measures
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
Eye Contact
minutes. Get medical attention.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
Skin Contact
and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
InhalationIf the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not
improve.
IngestionDO NOT INDUCE VOMITING. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing,
perform mouth-to-mouth resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible
indication that the toxic material was ingested; the absence of such signs, however, is not conclusive.
Continued on Next Page
Hydrazine Monohydrobromide
Section V.Fire and Explosion Data
Not available.
FlammabilityMay be combustible at high temperature.Auto-Ignition
Flammable LimitsNot available.
Flash PointsNot available.
Combustion ProductsThese products include nitrogen oxides (NOx), halogenated compounds.
Fire Hazards
Not available.
Risks of explosion of the product in presence of mechanical impact: Not available.
Explosion Hazards
Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
and Instructions
Consult with local fire authorities before attempting large scale fire-fighting operations.
Section VI.Accidental Release Measures
Toxic material. Corrosive material. This material is a skin sensitizer. Possibly carcinogenic material. Possibly mutagenic
Spill Cleanup
material. Hygroscopic material. Heat and shock sensitive material. Light sensitive material.
Instructions
Stop leak if without risk. DO NOT get water inside container. DO NOT touch spilled material. Use water spray to reduce
vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all sources of ignition. Consult
federal, state, and/or local authorities for assistance on disposal.
Section VII. Handling and Storage
Handling and StorageTOXIC. CORROSIVE. SENSITIZER. POSSIBLE CARCINOGEN. POSSIBLE MUTAGEN. HYGROSCOPIC. HEAT AND
SHOCK SENSITIVE. LIGHT SENSITIVE. Keep locked up.. Keep container dry. Keep away from heat. Mechanical exhaust
Information
required. When not in use, tightly seal the container and store in a dry, cool place. Avoid excessive heat and light. DO NOT
ingest. Do not breathe dust. Never add water to this product. Wear suitable protective clothing. If ingested, seek medical
advice immediately and show the container or the label. Treat symptomatically and supportively.
Always store away from incompatible compounds such as oxidizing agents, alkalis (bases), moisture.
Section VIII. Exposure Controls/Personal Protection
Engineering ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Face shield. Lab coat. Dust respirator. Boots. Gloves. A MSHA/NIOSH approved respirator must be used to avoid
Personal Protection
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
This chemical is classified as a possible carcinogen. There is no acceptable exposure limit for a carcinogen.
Exposure Limits
This compound is classified as a possible mutagen. There is no acceptable exposure limit for a mutagen.
Section IX. Physical and Chemical Properties
Physical state @ 20°CSolid. (White crystalline powder.)SolubilitySoluble in water.
Not available.
Specific Gravity
Molecular Weight112.96Partition CoefficientNot available.
Boiling PointNot available.Not applicable.
Vapor Pressure
Melting Point88°C (190.4°F)Vapor DensityNot available.
Not available.Not available.
Refractive IndexVolatility
Critical TemperatureNot available.OdorNot available.
Not available.Not available.
ViscosityTaste
Section X.Stability and Reactivity Data
StabilityThis material is stable if stored under proper conditions. (See Section VII for instructions)
Conditions of InstabilityAvoid excessive heat and light. Moisture sensitive. Hygroscopic; keep container tightly closed.
IncompatibilitiesReactive with oxidizing agents, alkalis (bases), moisture.
Continued on Next Page
Hydrazine Monohydrobromide
Section XI.Toxicological Information
RTECS NumberNot available.
Eye Contact. Ingestion. Inhalation. Skin contact.
Routes of Exposure
Toxicity DataNot available.
CARCINOGENIC EFFECTS : Not available.
Chronic Toxic Effects
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local
skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung
damage. Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in
one or many human organs.
Toxic if ingested or inhaled. Avoid prolonged contact with this material. Overexposure may result in serious illness or death.
Acute Toxic Effects
Corrosive to skin, eyes, and respiratory system. Liquid or spray mist may produce tissue damage, particularly in mucous
membranes of the eyes, mouth and respiratory tract. Skin contact may produce burns. Eye contact can result in corneal
damage or blindness. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking, or shortness of breath. Corrosive materials may cause serious injury if ingested.
Skin contact may result in sensitization. Always cover all exposed skin with an impermeable layer and use proper eye
protection. A OSHA/MSHA approved dust and vapor respirator is required when working with this material.
Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
Section XII.Ecological Information
EcotoxicityNot available.
Not available.
Environmental Fate
Section XIII. Disposal Considerations
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a
Waste Disposal
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
federal, state and local regulations when disposing of the substance.
Section XIV. Transport Information
DOT CLASS 6.1: Toxic material.
DOT Classification
DOT CLASS 8: Corrosive material
PIN Number
Proper Shipping NameToxic solid, corrosive, inorganic, n.o.s.
Packing Group (PG)II
DOT Pictograms
Section XV. Other Regulatory Information and Pictograms
TSCA Chemical InventoryThis compound is ON the EPA Toxic Substances Control Act (TSCA) inventory list.
(EPA)
WHMIS ClassificationCLASS D-1B: Material causing immediate and serious toxic effects (TOXIC).
CLASS E: Corrosive solid.
(Canada)
On NDSL.
EINECS Number (EEC) 237-412-7
EEC Risk StatementsR23/24/25- Toxic by inhalation, in contact with skin and if swallowed.
R34- Causes burns.
R45- May cause cancer.
R46- May cause heritable genetic damage.
R47- May cause birth defects.
Japanese Regulatory DataENCS No. 1-105; 1-374
Continued on Next Page
SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用的

2、摩尔体积（cm³/mol）：无可用的

3、等张比容（90.2K）：无可用的

4、表面张力（dyne/cm）：无可用的

5、介电常数：无可用的

6、极化率（10^-24cm³）：无可用的

7、单一同位素质量：111.963603 Da

8、标称质量：112 Da

9、平均质量：112.9571 Da

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:2

3.氢键受体数量:2

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积52

7.重原子数量:3

8.表面电荷:0

9.复杂度:0

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2