英语词典化工词典

mercury(2+),dinitrate

mercury(2+),dinitrate


  • 中文别名:硝酸汞(2+)
  • 中文释义:硝酸汞;硝酸汞(剧毒)
  • 英文别名:Nitric acid, mercury(2+) salt (2:1);
    Mercury(II) nitrate (Hg(NO3)2) (6CI);
    Nitric acid, mercury(2+) salt (8CI,9CI);
    Citrine ointment;
    Mercuric nitrate;
    Mercury dinitrate;
    Mercury nitrate;
    Mercury nitrate (Hg(NO3)2);
    Mercury(2+) nitrate;
    Mercury(II) nitrate;
    Millon's reagent;
    Named reagents and solutions, Millon's 
  • CAS No.:10045-94-0
  • 分子式:

    HgN2O6

  • 分子量:324.60000
  • 精确分子量:327.96192
  • PSA:137.76000
  • InChI:InChI=1/Hg.NO3/c;2-1(3)4/q+2;-1
  • 分子结构式:

物化性质

密度:
1.025 g/mL at 25 °C
熔点:
79ºC
沸点:
83ºC
蒸汽压:
49.8mmHg at 25°C
存储条件/存储方法:
库房通风低温干燥,轻装轻卸,与有机物、还原剂、硫、磷易燃物,食品原料分开存放
稳定性相关:

1.稳定性[9] 稳定

2.禁配物[10] 易燃或可燃物、强还原剂、无机物、磷、活性金属粉末等

3.避免接触的条件[11] 受热

4.聚合危害[12] 不聚合

5.分解产物[13] 氮氧化物、氧化汞

其它信息:

1.性状:无色或白色透明结晶,有潮解性。[1]

2.熔点(℃):79[2]

3.沸点(℃):180(分解)[3]

4.相对密度(水=1):4.39[4]

5.溶解性:易溶于水,不溶于乙醇,溶于硝酸。[5]

安全信息

密度:
1.025 g/mL at 25 °C
熔点:
79ºC
沸点:
83ºC
蒸汽压:
49.8mmHg at 25°C
存储条件/存储方法:
库房通风低温干燥,轻装轻卸,与有机物、还原剂、硫、磷易燃物,食品原料分开存放
稳定性相关:

1.稳定性[9] 稳定

2.禁配物[10] 易燃或可燃物、强还原剂、无机物、磷、活性金属粉末等

3.避免接触的条件[11] 受热

4.聚合危害[12] 不聚合

5.分解产物[13] 氮氧化物、氧化汞

其它信息:

1.性状:无色或白色透明结晶,有潮解性。[1]

2.熔点(℃):79[2]

3.沸点(℃):180(分解)[3]

4.相对密度(水=1):4.39[4]

5.溶解性:易溶于水,不溶于乙醇,溶于硝酸。[5]

毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OW8225000
CAS REGISTRY NUMBER :
10045-94-0
LAST UPDATED :
199712
DATA ITEMS CITED :
29
MOLECULAR FORMULA :
N2-O6.Hg
MOLECULAR WEIGHT :
324.61
WISWESSER LINE NOTATION :
HG N-O3*2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
26 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
75 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
25 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
7200 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
20 mg/kg
REFERENCE :
MOLAAF Monatsschrift fuer Ohrenheilkunde und Laryngo-Rhinologie. (Vienna, Austria) V.1-108, 1867-1974. For publisher information, see LROTDW. Volume(issue)/page/year: 73,751,1939 *** REVIEWS *** ACGIH TLV-TWA 0.025 mg(Hg)/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.05 mg(Hg)/m3 DTLWS* "Documentation of the Threshold Limit Values for Substances in Workroom Air," Supplements. For publisher information, see 85INA8. Volume(issue)/page/year: 3,22,1973 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.05 mg(Hg)/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.05 mg(Hg)/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-FINLAND:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-FRANCE:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-GERMANY:TWA 0.01 ppm (0.1 mg(Hg)/m3) JAN 1993 OEL-HUNGARY:TWA 0.02 mg(Hg)/m3;STEL 0.04 mg(Hg)/m3 JAN 1993 OEL-JAPAN:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.05 mg(Hg)/m3;STEL 0.15 mg(Hg)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-POLAND:TWA 0.01 mg(Hg)/m3 JAN 1993 OEL-RUSSIA:TWA 0.05 mg(Hg)/m3;STEL 0.01 mg(Hg)/m3 JAN 1993 OEL-SWEDEN:TWA 0.05 mg(Hg)/m3 JAN 1993 OEL-THAILAND:STEL 0.05 mg(Hg)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.05 mg(Hg)/m3;STEL 0.15 mg(Hg)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO MERCURY, ARYL AND INORGANIC-air:CL 0.1 mg/m3 (Sk)REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81005 No. of Facilities: 925 (estimated) No. of Industries: 9 No. of Occupations: 13 No. of Employees: 7651 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81005 No. of Facilities: 1345 (estimated) No. of Industries: 14 No. of Occupations: 17 No. of Employees: 13589 (estimated) No. of Female Employees: 6114 (estimated)
毒理学数据:

1.急性毒性[6]

LD50:26mg/kg(大鼠经口);75mg/kg(大鼠经皮)

2.刺激性 暂无资料

3.亚急性与慢性毒性[7] 动物的慢性中毒表现最早是行为改变,继而出现神经系统功能障碍,血液变化主要有白细胞增多、血沉加快,然后出现肝、肾功能受损。动物尸检见直肠下段溃疡,肝肾脂肪变性,肝有灶性坏死。

生态数据:

1.生态毒性 暂无资料

2.生物降解性 暂无资料

3.非生物降解性 暂无资料

4.其他有害作用[8] 该物质对环境有危害,应特别注意对水体的污染;汞元素在生物体内有很强的蓄积作用。

MSDS

第一部分:化学品名称

分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:6

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积126

7.重原子数量:9

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

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