英语词典化工词典

divanadium pentaoxide

divanadium pentaoxide


  • 中文别名:五氧化二钒
  • 中文释义:五氧化二钒;矾酸酐;钒(酸)酐;五氧化二矾;氧化矾;氧化钒;无水钒酸;五氧化钒;氧化钒(V);Phosphoric Pentoxide;tricyclo[3.3.1.1~3,7~]tetraphosphoxane 1,3,5,7-tetraoxide;1,3-dioxodiphosphoxane-1,3-diium-1,3-diolate;Phosphorus(Ⅴ)oxide;Phosphorous Pentoxide (P2O5);Phosphorus pentoxide;actox216;a
  • 英文别名:panadium pentaoxide;
    vanadium dichloride;
    Divanadium pentaoxide Divanadium pentoxide Pentaoxopanadium Vandia;
    Vanadium pentoxide;
    Divanadium pentaoxide Divanadium pentoxide Pentaoxopanadium Vandia vanadium 
  • CAS No.:1314-62-1
  • 分子式:

    O5V2

  • 分子量:181.88000
  • 精确分子量:181.86200
  • PSA:77.51000
  • MDL:MFCD00011457
  • InChI:InChI=1/5O.2V/rO5V2/c1-6(2)5-7(3)4
  • 分子结构式:

物化性质

外观与性状:
黄色至生锈-棕色片状
密度:
3.357
熔点:
690ºC
沸点:
1750ºC
闪点:
1750ºC
水溶解性:
1 g/125 mL
存储条件/存储方法:
库房通风低温干燥,与酸类,食品分开储运
稳定性相关:

1.五氧化二钒蒸气有毒!难溶于水,但生成钒酸,使溶液显酸性。此外,虽然难溶于硫酸和硝酸,但可溶于碱性水溶液。

2.可溶于盐酸并放出氯气,被还原成Ⅳ+氧化态。

其它信息:

1. 性状:橙黄色结晶性粉末或红棕色针状结晶粉末。

2. 密度(g/mL,25/4℃): 3.357

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):690

5. 沸点(ºC,常压):1750

6. 沸点(ºC,5.2kPa): 未确定

7. 折射率: 未确定

8. 闪点(ºC): 未确定

9. 比旋光度(º): 未确定

10. 自燃点或引燃温度(ºC): 未确定

11. 蒸气压(kPa,25ºC): 未确定

12. 饱和蒸气压(kPa,60ºC): 未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC): 未确定

15. 临界压力(KPa): 未确定

16. 油水(辛醇/水)分配系数的对数值: 未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V): 未确定

19. 溶解性:溶于浓酸、碱,微溶于水,不溶于无水乙醇。

安全信息

外观与性状:
黄色至生锈-棕色片状
密度:
3.357
熔点:
690ºC
沸点:
1750ºC
闪点:
1750ºC
水溶解性:
1 g/125 mL
存储条件/存储方法:
库房通风低温干燥,与酸类,食品分开储运
稳定性相关:

1.五氧化二钒蒸气有毒!难溶于水,但生成钒酸,使溶液显酸性。此外,虽然难溶于硫酸和硝酸,但可溶于碱性水溶液。

2.可溶于盐酸并放出氯气,被还原成Ⅳ+氧化态。

其它信息:

1. 性状:橙黄色结晶性粉末或红棕色针状结晶粉末。

2. 密度(g/mL,25/4℃): 3.357

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):690

5. 沸点(ºC,常压):1750

6. 沸点(ºC,5.2kPa): 未确定

7. 折射率: 未确定

8. 闪点(ºC): 未确定

9. 比旋光度(º): 未确定

10. 自燃点或引燃温度(ºC): 未确定

11. 蒸气压(kPa,25ºC): 未确定

12. 饱和蒸气压(kPa,60ºC): 未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC): 未确定

15. 临界压力(KPa): 未确定

16. 油水(辛醇/水)分配系数的对数值: 未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V): 未确定

19. 溶解性:溶于浓酸、碱,微溶于水,不溶于无水乙醇。

毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
YW2450000
CHEMICAL NAME :
Vanadium pentoxide (dust)
CAS REGISTRY NUMBER :
1314-62-1
LAST UPDATED :
199806
DATA ITEMS CITED :
55
MOLECULAR FORMULA :
O5-V2
MOLECULAR WEIGHT :
181.88
WISWESSER LINE NOTATION :
VA2 O5

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human
DOSE/DURATION :
346 mg/m3
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - cough Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - sputum
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human
DOSE/DURATION :
1 mg/m3/8H
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - cough Lungs, Thorax, or Respiration - bronchiolar constriction Sense Organs and Special Senses (Eye) - conjunctive irritation
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10 mg/kg
TOXIC EFFECTS :
Behavioral - coma
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
126 mg/m3/6H
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - ataxia Lungs, Thorax, or Respiration - dyspnea
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
12 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
14 mg/kg
TOXIC EFFECTS :
Behavioral - coma
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intratracheal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
6 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
23 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
10 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - cat
DOSE/DURATION :
500 mg/m3/23M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
50 mg/kg
TOXIC EFFECTS :
Liver - other changes Kidney, Ureter, Bladder - other changes
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
20 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
91 mg/kg/26W-I
TOXIC EFFECTS :
Behavioral - alteration of operant conditioning
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1280 mg/kg/15W-C
TOXIC EFFECTS :
Blood - pigmented or nucleated red blood cells Blood - changes in erythrocyte (RBC) count Skin and Appendages - hair
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
100 ug/m3/24H/24D-C
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Nutritional and Gross Metabolic - weight loss or decreased weight gain Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - phosphatases
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2 mg/m3/1H/13W-I
TOXIC EFFECTS :
Behavioral - alteration of classical conditioning
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
56 mg/kg/14D-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - other changes Biochemical - Metabolism (Intermediary) - lipids including transport
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intratracheal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7200 ug/kg/1Y-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - other changes Lungs, Thorax, or Respiration - changes in lung weight Biochemical - Metabolism (Intermediary) - amino acids (including renal excretion)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
90 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Effects on Embryo or Fetus - fetal death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
180 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - other effects to embryo
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
10 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Effects on Embryo or Fetus - fetal death Reproductive - Specific Developmental Abnormalities - other developmental abnormalities
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
10 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea) Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
50 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - skin and skin appendages Reproductive - Specific Developmental Abnormalities - musculoskeletal system Reproductive - Specific Developmental Abnormalities - other developmental abnormalities
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
5 mg/kg
SEX/DURATION :
female 10 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - skin and skin appendages Reproductive - Specific Developmental Abnormalities - musculoskeletal system Reproductive - Specific Developmental Abnormalities - other developmental abnormalities
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
85 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - musculoskeletal system Reproductive - Specific Developmental Abnormalities - other developmental abnormalities
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
85 mg/kg
SEX/DURATION :
female 6-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - other effects to embryo
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
170 mg/kg
SEX/DURATION :
male 60 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured before birth) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
170 mg/kg
SEX/DURATION :
male 60 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct Reproductive - Fertility - male fertility index (e.g. # males impregnating females per # males exposed to fertile nonpregnant females)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intravenous
DOSE :
10900 mg/kg
SEX/DURATION :
female 8 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - musculoskeletal system

MUTATION DATA

TYPE OF TEST :
Micronucleus test
TEST SYSTEM :
Rodent - hamster Lung
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 321,35,1994 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 0.05 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW FRMBAZ Farmacia (Bucharest). (Rompresfilatelia, POB 12-201, Bucharest, Romania) V.1- 1953- Volume(issue)/page/year: 21,325,1973 TOXICOLOGY REVIEW 85DHAX "Medical and Biologic Effects of Environmental Pollutants Series," Washington, DC, National Academy of Sciences, 1972-77 Volume(issue)/page/year: V,46,1974 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:CL 0.5 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,275,1971 OSHA PEL (Gen Indu):CL 0.5 mg(V2O5)/m3, respirable dust CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 0.5 mg(V2O5)/m3, respirable fraction CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 0.5 mg(V2O5)/m3, respirable fraction CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 0.5 mg(V2O5)/m3, respirable fraction CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO VANADIUM (as V2O5), resp dust/fume-air:CL 0.05 mg/m3/15MREFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 76210 No. of Facilities: 333 (estimated) No. of Industries: 7 No. of Occupations: 12 No. of Employees: 2562 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 76210 No. of Facilities: 67 (estimated) No. of Industries: 6 No. of Occupations: 17 No. of Employees: 4468 (estimated) No. of Female Employees: 541 (estimated)
毒理学数据:

急性毒性:小鼠口经LD50:5mg/kg;大鼠口经LD50:10mg/kg;小兔皮层组织LD50:50mg/kg;大鼠吸入LC50:126mg/m3/6H
对呼吸系统和皮肤有损害作用。

生态数据:

水危害级别3:对水是极其危害的,即使是少量产品渗入地下也会对饮用水造成危害,若无政府许可勿将产品排入周围环境。对水中有机物有剧毒和危害

MSDS

第一部分:化学品名称
化学品中文名称:五氧化二钒;钒酸酐
化学品英文名称:Vanadium pentoxide
中文俗名或商品名:
Synonyms:
CAS No.:1314-62-1
分子式:V2O5
分子量:182
第二部分:成分/组成信息
纯化学品 混合物
化学品名称:五氧化二钒;钒酸酐
有害物成分含量CAS No.
五氧化二钒≥99.0%1314-62-1
第三部分:危险性概述
危险性类别:第6.1类 毒害品
侵入途径:吸入 食入 经皮吸收
健康危害:对呼吸系统和皮肤有损害作用。急性中毒:可引起鼻、咽、肺部刺激症状,多数工人有咽痒、干咳、胸闷、全身不适、倦怠等表现,部分患者可引起肾炎、肺炎。慢性中毒:长期接触可引起慢性支气管炎、肾损害、视力障碍等。
环境危害:
燃爆危险:本品不燃,高毒。
第四部分:急救措施
皮肤接触:脱去污染的衣着,立即用流动清水彻底冲洗。
眼睛接触:立即提起眼睑,用流动清水冲洗。
吸入:脱离现场至空气新鲜处。注意保暖,必要时进行人工呼吸。就医。
食入:误服者给饮大量温水,催吐,就医。
第五部分:消防措施
危险特性:不燃。与三氟化氯、锂接触剧烈反应。
有害燃烧产物:可能产生有害的毒性烟雾。
灭火方法及灭火剂:不燃。火场周围可用的灭火介质。
消防员的个体防护:消防人员必须穿全身防火防毒服,在上风向灭火。灭火时尽可能将容器从火场移至空旷处。
禁止使用的灭火剂:
闪点(℃):无意义
自燃温度(℃):无意义
爆炸下限[%(V/V)]:无意义
爆炸上限[%(V/V)]:无意义
最小点火能(mJ):
爆燃点:
爆速:
最大燃爆压力(MPa):
建规火险分级:
第六部分:泄漏应急处理
应急处理:隔离泄漏污染区,周围设警告标志,建议应急处理人员戴正压自给式呼吸器,穿化学防护服。不要直接接触泄漏物,避免扬尘,用清洁的铲子收集于干燥净洁有盖的容器中,转移到安全场所。也可以用水泥、沥青或适当的热塑性材料固化处理再废弃。如大量泄漏,收集回收或无害处理后废弃。
第七部分:操作处置与储存
操作注意事项:密闭操作,局部排风。操作人员必须经过专门培训,严格遵守操作规程。建议操作人员佩戴防尘面具(全面罩),穿胶布防毒衣,戴橡胶手套。远离易燃、可燃物。避免产生粉尘。避免与酸类接触。搬运时要轻装轻卸,防止包装及容器损坏。配备泄漏应急处理设备。倒空的容器可能残留有害物。
储存注意事项:储存于阴凉、通风的库房。远离火种、热源。应与易(可)燃物、酸类、食用化学品分开存放,切忌混储。储区应备有合适的材料收容泄漏物。应严格执行极毒物品“五双”管理制度。
第八部分:接触控制/个体防护
最高容许浓度:中国MAC:0.1mg/m3[烟]苏联MAC:0.1mg/m3[烟]美国TWA:OSHA 0
监测方法:N-肉桂酸-邻-甲苯羟胺分光光度法;N-肉桂酸-邻-甲苯羟胺比色法
工程控制:密闭操作,局部排风。
呼吸系统防护:空气中浓度超标时,应该佩带防毒面具。必要时佩带自给式呼吸器。
眼睛防护:戴化学安全防护眼镜。
身体防护:穿相应的防护服。
手防护:戴防护手套。
其他防护:工作现场禁止吸烟、进食和饮水。工作后,淋浴更衣。单独存放被毒物污染的衣服,洗后再用。进行就业前和定期
第九部分:理化特性
外观与性状:橙黄色或红棕色结晶粉末。
pH:无资料
熔点(℃):690
沸点(℃):分解
相对密度(水=1):3.35
相对蒸气密度(空气=1):无资料
饱和蒸气压(kPa):无资料
燃烧热(kJ/mol):无意义
临界温度(℃):分解温度(℃):1750
临界压力(MPa):无资料
辛醇/水分配系数的对数值:无资料
闪点(℃):无意义
引燃温度(℃):无意义
爆炸上限%(V/V):无意义
爆炸下限%(V/V):无意义
分子式:V2O5
分子量:182
蒸发速率:
粘性:
溶解性:微溶于水,不溶于乙醇,溶于浓酸、碱。
主要用途:广泛用于有机合成工业及硫酸工业中,也用作玻璃搪瓷着色剂,磁性材料。
第十部分:稳定性和反应活性
稳定性:在常温常压下 稳定
禁配物:强酸、易燃或可燃物。
避免接触的条件:
聚合危害:不能出现
分解产物:可能产生有害的毒性烟雾。
第十一部分:毒理学资料
急性毒性:属高毒类LD50:10mg/kg(大鼠经口) LC50:无资料
急性中毒:
慢性中毒:
亚急性和慢性毒性:
刺激性:
致敏性:
致突变性:
致畸性:
致癌性:
第十二部分:生态学资料
生态毒理毒性:
生物降解性:
非生物降解性:
生物富集或生物积累性:
第十三部分:废弃处置
废弃物性质:
废弃处置方法:
废弃注意事项:
第十四部分:运输信息
危险货物编号:61028
UN编号:2862
包装标志:
包装类别:
包装方法:
运输注意事项:储存于阴凉、通风仓间内。远离火种、热源。防止阳光直射。包装必须密封,切勿受潮。应与碱类、酸类、氧化剂等分开存放。不可混储混运。搬运时要轻装轻卸,防止包装及容器损坏。分装和搬运作业要注意个人防护。
RETCS号:
IMDG规则页码:
第十五部分:法规信息
国内化学品安全管理法规:化学危险物品安全管理条例 (1987年2月17日国务院发布),化学危险物品安全管理条例实施细则 (化劳发[1992] 677号),工作场所安全使用化学品规定 ([1996]劳部发423号)等法规,针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定;常用危险化学品的分类及标志 (GB 13690-92)将该物质划为第6.1 类毒害品;剧毒物品分级、分类与品名编号(GA 57-93)中,该物质属第三类 B级无机剧毒品。
国际化学品安全管理法规:
第十六部分:其他信息
参考文献:1.周国泰,化学危险品安全技术全书,化学工业出版社,1997 2.国家环保局有毒化学品管理办公室、北京化工研究院合编,化学品毒性法规环境数据手册,中国环境科学出版社.1992 3.Canadian Centre for Occupational Health and Safety,CHEMINFO Database.1998 4.Canadian Centre for Occupational Health and Safety, RTECS Database, 1989
填表时间:年月日
填表部门:
数据审核单位:
修改说明:
其他信息:1
MSDS修改日期:年月日

分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:181.862501 Da

8、标称质量:182 Da

9、平均质量:181.88 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:5

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积77.5

7.重原子数量:7

8.表面电荷:0

9.复杂度:124

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

热门化工词典词汇