1-Hexanamine,N,N-dihexyl-

物化性质

外观与性状：

无色至淡黄色液体

密度：

0.794 g/mL at 25 °C(lit.)

熔点：

<-75ºC

沸点：

150-159 °C12 mm Hg(lit.)

闪点：

>230 °F

折射率：

n20/D 1.442(lit.)

蒸汽压：

0.0103mmHg at 25°C

蒸汽密度：

9.3 (vs air)

存储条件/存储方法：

储存于阴凉、通风的库房。远离火种、热源。应与氧化剂、酸性物质等分开存放，切忌混储。配备相应品种和数量的消防器材。储区应备有泄漏应急处理设备和合适的收容材料。

稳定性相关：

避免与强氧化剂、酸接触。使用时应穿防护服。

其它信息：

1. 性状：无色液体，类似胺气味。

2. 密度（g/mL,20/4℃）：0.798

3. 相对蒸汽密度（g/mL,空气=1）：9.3

4. 熔点（ºC）：<-75

5. 沸点（ºC,常压）：163~265

6. 沸点（ºC,1.6KPa）：150~159

7. 折射率（20ºC）：1.442

8. 闪点（ºC）：144

9. 自燃点或引燃温度（ºC）：230

10. 蒸气压（mmHg,20ºC）：<1

11. 爆炸上限（%,V/V）：2.4

12. 爆炸下限（%,V/V）：0.2

13. 溶解性：易溶于乙醇、乙醚，能溶于酸，微溶于水。

安全信息

外观与性状：

无色至淡黄色液体

密度：

0.794 g/mL at 25 °C(lit.)

熔点：

<-75ºC

沸点：

150-159 °C12 mm Hg(lit.)

闪点：

>230 °F

折射率：

n20/D 1.442(lit.)

蒸汽压：

0.0103mmHg at 25°C

蒸汽密度：

9.3 (vs air)

存储条件/存储方法：

储存于阴凉、通风的库房。远离火种、热源。应与氧化剂、酸性物质等分开存放，切忌混储。配备相应品种和数量的消防器材。储区应备有泄漏应急处理设备和合适的收容材料。

稳定性相关：

避免与强氧化剂、酸接触。使用时应穿防护服。

其它信息：

1. 性状：无色液体，类似胺气味。

2. 密度（g/mL,20/4℃）：0.798

3. 相对蒸汽密度（g/mL,空气=1）：9.3

4. 熔点（ºC）：<-75

5. 沸点（ºC,常压）：163~265

6. 沸点（ºC,1.6KPa）：150~159

7. 折射率（20ºC）：1.442

8. 闪点（ºC）：144

9. 自燃点或引燃温度（ºC）：230

10. 蒸气压（mmHg,20ºC）：<1

11. 爆炸上限（%,V/V）：2.4

12. 爆炸下限（%,V/V）：0.2

13. 溶解性：易溶于乙醇、乙醚，能溶于酸，微溶于水。

毒理性

毒理学数据：

1、 急性毒性：大鼠经口LD50：1150mg/kg

2、口服有毒。对眼睛、呼吸系统及皮肤有刺激性。

生态数据：

该物质对环境有危害，应特别注意对水体的污染。对水生物有毒。能对水环境引起不利的结果。

MSDS

Name:	Trihexylamine 98% Material Safety Data Sheet
Synonym:
CAS:	102-86-3

Section 1 - Chemical Product   MSDS Name:Trihexylamine 98% Material Safety Data Sheet
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
102-86-3	Trihexylamine	98%	203-062-9

Hazard Symbols: None Listed.
Risk Phrases: None Listed.
Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 102-86-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: < 1 mm Hg @ 20 deg
Viscosity: Not available.
Boiling Point: 263 - 265 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .7984g/cm3
Molecular Formula: C18H39N
Molecular Weight: 269.51
Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 102-86-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Trihexylamine - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
 
Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 8
UN Number: 2735
Packing Group: III
IMO
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: III
RID/ADR
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing group: III
Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 102-86-3: No information available.
Canada
CAS# 102-86-3 is listed on Canada's DSL List.
CAS# 102-86-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 102-86-3 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

海关数据

中国海关编码：2921199090

概述：

2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

申报要素：

品名, 成分含量, 用途

摘要/Summary：

2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

分子结构与计算化学数据

分子结构数据

1、 摩尔折射率：89.16

2、 摩尔体积（cm³/mol）：332.9

3、 等张比容（90.2K）：733.9

4、 表面张力（dyne/cm）：29.2

5、 介电常数：

6、 偶极距（10^-24cm³）：

7、 极化率：35.34

计算化学数据

1.疏水参数计算参考值（XlogP）:7.3

2.氢键供体数量:0

3.氢键受体数量:1

4.可旋转化学键数量:15

5.互变异构体数量:无

6.拓扑分子极性表面积3.2

7.重原子数量:19

8.表面电荷:0

9.复杂度:127

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1