4H-Dibenzo[de,g]quinoline-10,11-diol,5,6,6a,7-tetrahydro-, (6aR)-
- 中文别名：6-庚炔醇
- 中文释义：(6aR)-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline-10,11-diol
- 英文别名：(6aR)-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline-10,11-diol;
Norapomorphine;
4H-Dibenzo(de,g)quinoline-10,11-diol,5,6,6a,7-tetrahydro-,(R)
- CAS No.：478-76-2
- 分子式：C16H15NO2
- 分子量：334.21
- 精确分子量：253.11000
- PSA：52.49000
- InChI：The Key: MHPQCGZBAVXCGA-UHFFFAOYSA-N
- 分子结构式：
物化性质
- 危险类别码：
- 20/21/22-36/37/38
- 安全说明：
- 26-36
安全信息
- 危险类别码：
- 20/21/22-36/37/38
- 安全说明：
- 26-36
MSDS
Date Updated: 06/FEB/2006
Version 1.2
Regulation (EC) No 1907/2006
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1 - Product and Company Information
________________________________________________________________________
Product NameR(-)-NORAPOMORPHINE HBR
Product NumberD040
Company
Century Ba-Shi Building 22A-B,
200020 Shanghai
Technical Phone #86-21-61415566
Fax 86-21-61415567
E-mail Address
________________________________________________________________________
2 - Hazards Identification
________________________________________________________________________
SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
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3 - Composition/Information on Ingredients
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Product NameCAS #EC noAnnex I
Index Number
R(-)-NORAPOMORPHINE HYDROBROMIDE NoneNoneNone
Ingredient NamePercent CAS #EC noAnnex I
Index Number
THE FOLLOWING SUBSTANCESNoneNoneNone
ARE PRESENT AS RESIDUAL
COMPONENTS OF PRODUCTION.
DIETHYL ETHER, INHIBITOR 160-29-7200-467-2 603-022-00-4
FREE
Symbols: F+-Xn
R-Phrases: 12-19-22-66-67
Extremely flammable. May form explosive peroxides. Harmful if
swallowed. Repeated exposure may cause skin dryness or cracking.
Vapors may cause drowsiness and dizziness.
FormulaC16H15NO2 HBr
Molecular Weight 334,2000 AMU
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4 - First Aid Measures
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AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician.
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5 - Fire Fighting Measures
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EXTINGUISHING MEDIA
Suitable: Water spray. Carbon dioxide, dry chemical powder, or
appropriate foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.
________________________________________________________________________
6 - Accidental Release Measures
________________________________________________________________________
PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear respirator, chemical safety goggles, rubber boots, and
heavy rubber gloves.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid
raising dust. Ventilate area and wash spill site after material
pickup is complete.
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7 - Handling and Storage
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HANDLING
Directions for Safe Handling: Do not breathe dust. Avoid contact
with eyes, skin, and clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed. Store in the dark.
Store at 2-8°C
________________________________________________________________________
8 - Exposure Controls / Personal Protection
________________________________________________________________________
ENGINEERING CONTROLS
Safety shower and eye bath. Mechanical exhaust required.
GENERAL HYGIENE MEASURES
Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Where risk assessment shows air-purifying respirators
are appropriate use a dust mask type N95 (US) or type P1 (EN 143)
respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
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9 - Physical and Chemical Properties
________________________________________________________________________
AppearancePhysical State: Solid
Color: Slightly brown
PropertyValueAt Temperature or Pressure
pH N/A
BP/BP RangeN/A
MP/MP Range249,000. - 252,000 °
C.
Flash PointN/A
FlammabilityN/A
Autoignition TempN/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion LimitsN/A
Vapor PressureN/A
Partition Coefficient N/A
ViscosityN/A
Vapor DensityN/A
Saturated Vapor Conc. N/A
Evaporation RateN/A
Bulk DensityN/A
Decomposition Temp.N/A
Solvent ContentN/A
Water ContentN/A
Surface TensionN/A
ConductivityN/A
Miscellaneous DataN/A
SolubilityN/A
________________________________________________________________________
10 - Stability and Reactivity
________________________________________________________________________
STABILITY
Stable: Stable.
Conditions to Avoid: Light.
Materials to Avoid: Oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Nitrogen oxides, Hydrogen bromide gas.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
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11 - Toxicological Information
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SIGNS AND SYMPTOMS OF EXPOSURE
Contact with eyes can cause redness, tearing, and blurred
vision. Prolonged or repeated contact with skin can cause
defatting and dermatitis. Exposure can cause: Coughing, chest
pains, difficulty in breathing. To the best of our knowledge,
the chemical, physical, and toxicological properties have not
been thoroughly investigated.
ROUTE OF EXPOSURE
Skin Contact: Causes skin irritation.
Skin Absorption: Harmful if absorbed through skin.
Eye Contact: Causes eye irritation.
Inhalation: Harmful if inhaled. Material is irritating to mucous
membranes and upper respiratory tract.
Ingestion: Harmful if swallowed.
TARGET ORGAN INFORMATION
Skeletal muscle. Central nervous system. Kidneys. Liver. G.I.
System.
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12 - Ecological Information
________________________________________________________________________
No data available.
________________________________________________________________________
13 - Disposal Considerations
________________________________________________________________________
SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
________________________________________________________________________
14 - Transport Information
________________________________________________________________________
RID/ADR
Non-hazardous for road transport.
IMDG
Non-hazardous for sea transport.
IATA
Non-hazardous for air transport.
________________________________________________________________________
15 - Regulatory Information
________________________________________________________________________
CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: Xn
Harmful.
R-PHRASES: 20/21/22-36/37/38
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
S-PHRASES: 26-36
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. Wear suitable protective
clothing.
Caution: Substance not yet fully tested (EU).
COUNTRY SPECIFIC INFORMATION
Germany
WGK: No hazard to waters.
Self-Classification
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16 - Other Information
________________________________________________________________________
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
模块 15 - 法规信息
N/A
模块16 - 其他信息
N/A
