3,5-Dibromobenzyl bromide
- 中文别名:3,5-二溴溴苄
- 中文释义:3,5-二溴苄基溴;3,5-二溴溴苄;3,5-二溴苄溴;α,3,5-三溴甲苯
- 英文别名:3,5-Dibromobenzyl bromide;
1,3-dibromo-5-(bromomethyl)benzene
- CAS No.:56908-88-4
- 分子式:C7H5Br3
- 分子量:328.83
- 精确分子量:325.79400
- PSA:0.00000
- MDL:MFCD00052415
- InChI:InChI=1/C7H5Br3/c8-4-5-1-6(9)3-7(10)2-5/h1-3H,4H2
- 分子结构式:
物化性质
- 外观与性状:
- 白色至米色-褐色粉末
- 密度:
- 2.173 g/cm3
- 熔点:
- 93-97 °C
- 沸点:
- 316.5ºC at 760 mmHg
- 闪点:
- 142.2°C
- 折射率:
- 1.636
- 存储条件/存储方法:
保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置
- 稳定性相关:
如果遵照规格使用和储存则不会分解,未有已知危险反应
- 其它信息:
1. 性状:固体
2. 密度(g/mL,15ºC):未确定
3. 相对蒸汽密度(g/mL,空气=1): 未确定
4. 熔点(ºC):88-90
5. 沸点(ºC):未确定
6. 沸点(ºC,10mmHg):未确定
7. 折射率:未确定
8. 闪点(°F):未确定
9. 比旋光度(ºC):未确定
10. 自燃点或引燃温度(ºC): 未确定
11. 蒸气压(kPa,25ºC):未确定
12. 饱和蒸气压(kPa,60ºC):未确定
13. 燃烧热(KJ/mol):未确定
14. 临界温度(ºC):未确定
15. 临界压力(KPa):未确定
16. 油水(辛醇/水)分配系数的对数值:未确定
17. 爆炸上限(%,V/V):未确定
18. 爆炸下限(%,V/V):未确定
19. 溶解性:未确定
安全信息
- 外观与性状:
- 白色至米色-褐色粉末
- 密度:
- 2.173 g/cm3
- 熔点:
- 93-97 °C
- 沸点:
- 316.5ºC at 760 mmHg
- 闪点:
- 142.2°C
- 折射率:
- 1.636
- 存储条件/存储方法:
保持贮藏器密封、储存在阴凉、干燥的地方,确保工作间有良好的通风或排气装置
- 稳定性相关:
如果遵照规格使用和储存则不会分解,未有已知危险反应
- 其它信息:
1. 性状:固体
2. 密度(g/mL,15ºC):未确定
3. 相对蒸汽密度(g/mL,空气=1): 未确定
4. 熔点(ºC):88-90
5. 沸点(ºC):未确定
6. 沸点(ºC,10mmHg):未确定
7. 折射率:未确定
8. 闪点(°F):未确定
9. 比旋光度(ºC):未确定
10. 自燃点或引燃温度(ºC): 未确定
11. 蒸气压(kPa,25ºC):未确定
12. 饱和蒸气压(kPa,60ºC):未确定
13. 燃烧热(KJ/mol):未确定
14. 临界温度(ºC):未确定
15. 临界压力(KPa):未确定
16. 油水(辛醇/水)分配系数的对数值:未确定
17. 爆炸上限(%,V/V):未确定
18. 爆炸下限(%,V/V):未确定
19. 溶解性:未确定
毒理性
- 生态数据:
对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统,若无政府许可,勿将材料排入周围环境
MSDS
Name: | 3 5-Dibromobenzyl bromide Material Safety Data Sheet |
Synonym: | alpha,3,5-Tribromobenzyl bromide; 1,3-Dibromo-5-(bromomethyl)benzen |
CAS: | 56908-88-4 |
Section 1 - Chemical Product MSDS Name:3 5-Dibromobenzyl bromide Material Safety Data Sheet
Synonym:alpha,3,5-Tribromobenzyl bromide; 1,3-Dibromo-5-(bromomethyl)benzen
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# | Chemical Name | content | EINECS# |
56908-88-4 | 3,5-Dibromobenzyl bromide | 97% | unlisted |
Hazard Symbols: F C
Risk Phrases: 11 34
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Causes burns.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow of tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable solid.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Remove all sources of ignition. Use a spark-proof tool.
Section 7 - HANDLING and STORAGE
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area. Corrosives area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 56908-88-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white crystalline solid
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 88 - 90 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H5Br3
Molecular Weight: 329
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
No information found.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Water, oxidizing agents, bases, alcohols, amines, steel.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide, bromine.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 56908-88-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3,5-Dibromobenzyl bromide - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 56908-88-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 56908-88-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 56908-88-4 is not listed on the TSCA inventory.
It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
N/A
海关数据
中国海关编码:2903999090
- 概述:
- 2903999090 其他芳烃卤化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
- 申报要素:
- 品名, 成分含量, 用途
- 摘要/Summary:
- 2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
分子结构与计算化学数据
计算化学数据
1.疏水参数计算参考值(XlogP):3.9
2.氢键供体数量:0
3.氢键受体数量:0
4.可旋转化学键数量:1
5.互变异构体数量:无
6.拓扑分子极性表面积0
7.重原子数量:10
8.表面电荷:0
9.复杂度:95
10.同位素原子数量:0
11.确定原子立构中心数量:0
12.不确定原子立构中心数量:0
13.确定化学键立构中心数量:0
14.不确定化学键立构中心数量:0
15.共价键单元数量:1