antimony trisulfide

物化性质

外观与性状：

橙色粉末

密度：

4.64 g/mL at 25ºC(lit.)

熔点：

550ºC

沸点：

1150ºC

蒸汽压：

12600mmHg at 25°C

存储条件/存储方法：

库房通风低温干燥,与酸类,食品分开储运

稳定性相关：

1.如果遵照规格使用和储存则不会分解，未有已知危险反应，避免酸、水分/潮湿。不溶于水、醋酸。溶于浓盐酸、醇、硫氢化铵（ＮＨ４ＨＳ）、硫化钾溶液。无定形产品为橙红色粉末，相对密度4.15。熔点546～554℃。感光性强。具有半导体特性。不溶于水。溶于浓盐酸、碱金属氢氧化物水溶液。锑及其化合物可引起皮肤、角膜炎、结晶膜炎。吸入其蒸气或粉末可引起鼻黏膜溃疡。

2.稳定性^[8] 稳定

3.禁配物^[9] 氧化剂、酸类

4.避免接触的条件^[10] 潮湿空气、受热

5.聚合危害^[11] 不聚合

其它信息：

1.性状：红色粉末^[1]

2.熔点（℃）：550~563^[2]

3.沸点（℃）：1150^[3]

4.相对密度（水=1）：4.62^[4]

5.溶解性：不溶于水，溶于浓盐酸、硫酸。^[5]

安全信息

外观与性状：

橙色粉末

密度：

4.64 g/mL at 25ºC(lit.)

熔点：

550ºC

沸点：

1150ºC

蒸汽压：

12600mmHg at 25°C

存储条件/存储方法：

库房通风低温干燥,与酸类,食品分开储运

稳定性相关：

1.如果遵照规格使用和储存则不会分解，未有已知危险反应，避免酸、水分/潮湿。不溶于水、醋酸。溶于浓盐酸、醇、硫氢化铵（ＮＨ４ＨＳ）、硫化钾溶液。无定形产品为橙红色粉末，相对密度4.15。熔点546～554℃。感光性强。具有半导体特性。不溶于水。溶于浓盐酸、碱金属氢氧化物水溶液。锑及其化合物可引起皮肤、角膜炎、结晶膜炎。吸入其蒸气或粉末可引起鼻黏膜溃疡。

2.稳定性^[8] 稳定

3.禁配物^[9] 氧化剂、酸类

4.避免接触的条件^[10] 潮湿空气、受热

5.聚合危害^[11] 不聚合

其它信息：

1.性状：红色粉末^[1]

2.熔点（℃）：550~563^[2]

3.沸点（℃）：1150^[3]

4.相对密度（水=1）：4.62^[4]

5.溶解性：不溶于水，溶于浓盐酸、硫酸。^[5]

毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :

CC9450000

CHEMICAL NAME :

Antimony trisulfide

CAS REGISTRY NUMBER :

1345-04-6

LAST UPDATED :

199712

DATA ITEMS CITED :

38

MOLECULAR FORMULA :

S3-Sb2

MOLECULAR WEIGHT :

339.68

WISWESSER LINE NOTATION :

SB2 S3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Human

DOSE/DURATION :

580 ug/m3/35W

TOXIC EFFECTS :

Cardiac - EKG changes not diagnostic of specified effects Vascular - BP elevation not characterized in autonomic section Gastrointestinal - ulceration or bleeding from stomach

REFERENCE :

IMSUAI Industrial Medicine and Surgery. (Northbrook, IL) V.18-42, 1949-73. For publisher information, see IOHSA5. Volume(issue)/page/year: 23,521,1954

TYPE OF TEST :

LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

1390 mg/kg

TOXIC EFFECTS :

Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :

INMEAF Industrial Medicine. (Chicago, IL) V.1-18, 1932-49. For publisher information, see IOHSA5. Volume(issue)/page/year: 10,15,1941

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

209 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,23,1982

TYPE OF TEST :

LD - Lethal dose

ROUTE OF EXPOSURE :

Subcutaneous

SPECIES OBSERVED :

Mammal - species unspecified

DOSE/DURATION :

>139 mg/kg

REFERENCE :

GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 8(7),25,1964 *** REVIEWS *** ACGIH TLV-TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 47,291,1989 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 47,291,1989 IARC Cancer Review:Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 47,291,1989 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,15,1971 OSHA PEL (Gen Indu):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-BELGIUM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-DENMARK:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-FINLAND:.TWA (0.5 mg(Sb)/m3) JAN 1993 OEL-FRANCE:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-GERMANY:TWA 0.5 mg(Sb)/m3 (total dust) JAN 1993 OEL-HUNGARY:STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-RUSSIA:STEL 1 mg/m3 JAN 1993 OEL-RUSSIA:TWA 0.2 mg(Sb)/m3;STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-UNITED KINGDOM:STEL 0.5 ppm JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ANTIMONY-air:10H TWA 0.5 mg(Sb)/m3REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M4884 No. of Facilities: 786 (estimated) No. of Industries: 34 No. of Occupations: 27 No. of Employees: 26669 (estimated) No. of Female Employees: 1082 (estimated)

毒理学数据：

1.急性毒性^[6] LD50：209mg/kg（小鼠腹腔）

2.刺激性 暂无资料

3.致癌性^[7] IARC致癌性评论：G3，对人及动物致癌性证据不足。

生态数据：

水危害级别3：对水是极其危害的，即使是少量产品渗入地下也会对饮用水造成危害，若无政府许可勿将产品排入周围环境。对水中有机物有剧毒和危害。

MSDS

第一部分：化学品名称

分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用的

2、摩尔体积（cm³/mol）：无可用的

3、等张比容（90.2K）：无可用的

4、表面张力（dyne/cm）：无可用的

5、介电常数：无可用的

6、极化率（10^-24cm³）：无可用的

7、单一同位素质量：337.723854 Da

8、标称质量：338 Da

9、平均质量：339.715 Da

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:0

3.氢键受体数量:6

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积152

7.重原子数量:10

8.表面电荷:0

9.复杂度:84.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1