cadmium arsenide

物化性质

熔点：

721℃

存储条件/存储方法：

密封于阴凉干燥处。

稳定性相关：

遵照规格使用和储存则不会分解。

不溶于水，微溶于盐酸，溶于硝酸；但不溶于王水。

其它信息：

1. 性状：灰黑色立方晶体。

2. 密度（g/mL,20℃）： 6.211

3. 相对蒸汽密度（g/mL,空气=1）：无可用

4. 熔点（ºC）：721

5. 沸点（ºC,常压）：无可用

6. 沸点（ºC,5.2kPa）： 无可用

7. 折射率： 无可用

8. 闪点（ºC）： 无可用

9. 比旋光度（º）：无可用

10. 自燃点或引燃温度（ºC）：无可用

11. 蒸气压（kPa,25ºC）：无可用

12. 饱和蒸气压（kPa,60ºC）：无可用

13. 燃烧热（KJ/mol）：无可用

14. 临界温度（ºC）：无可用

15. 临界压力（KPa）：无可用

16. 油水（辛醇/水）分配系数的对数值：无可用

17. 爆炸上限（%,V/V）：无可用

18. 爆炸下限（%,V/V）： 无可用

19. 溶解性：在水中分解

安全信息

熔点：

721℃

存储条件/存储方法：

密封于阴凉干燥处。

稳定性相关：

遵照规格使用和储存则不会分解。

不溶于水，微溶于盐酸，溶于硝酸；但不溶于王水。

其它信息：

1. 性状：灰黑色立方晶体。

2. 密度（g/mL,20℃）： 6.211

3. 相对蒸汽密度（g/mL,空气=1）：无可用

4. 熔点（ºC）：721

5. 沸点（ºC,常压）：无可用

6. 沸点（ºC,5.2kPa）： 无可用

7. 折射率： 无可用

8. 闪点（ºC）： 无可用

9. 比旋光度（º）：无可用

10. 自燃点或引燃温度（ºC）：无可用

11. 蒸气压（kPa,25ºC）：无可用

12. 饱和蒸气压（kPa,60ºC）：无可用

13. 燃烧热（KJ/mol）：无可用

14. 临界温度（ºC）：无可用

15. 临界压力（KPa）：无可用

16. 油水（辛醇/水）分配系数的对数值：无可用

17. 爆炸上限（%,V/V）：无可用

18. 爆炸下限（%,V/V）： 无可用

19. 溶解性：在水中分解

毒理性

生态数据：

该物质对环境可能有危害，对水体应给予特别注意。

MSDS

Section 1: Product Identification
Chemical Name:Cadmium arsenide (99.999%-Cd) PURATREM
CAS Registry Number:12006-15-4
Formula:Cd3As2
EINECS Number:234-484-1
Chemical Family:metal arsenide
Synonym:Cadmium diarsenide
Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound12006-15-4100%0.002mg/m30.005mg/m3
Section 3: Hazards Identification
Danger of serious damage to health by prolonged exposure through inhalation and if swallowed. May cause
Emergency Overview:
harm to the unborn child.
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes
Eye Contact:May cause mild to severe irritation of the eyes.
Skin Contact:May cause slight to mild irritation of the skin. Harmful in contact with skin.
Inhalation:Harmful by inhalation. Danger of serious damage to health by prolonged exposure through inhalation.
Harmful if swallowed. Ingestion may lead to sudden nausea, vomiting, bloody diarrhea, weakness, convulsions
Ingestion:
and death.
Inhalation may cause metallic taste, cough, chest pain, fever, shills, pulmonary edema, liver and kidney
Acute Health Affects:
damage. Ingestion causes garlic breath odor, nausea, vomiting, bloody diarrhea, weakness. .
Prolonged exposure to cadmium compounds may result in kidney damage, anemia, pulmonary fibrosis,
emphysema, perforation of the nasal septum, loss of smell, male reproductive effects and an increased risk of
Chronic Health Affects:
cancer of the lungs, prostate and liver. Prolonged exposure to arsenic compounds may cause loss of appetite,
dermatitis, liver and kidney damage, nervous disorders and cancer of the skin, lungs and liver.
NTP:Yes
IARC:Yes
OSHA:Yes
SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire, this material may emit toxic fumes containing cadmium and arsenic.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
Spill and Leak Procedures:
swept up.
SECTION 7: Handling and Storage
Store the material in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep in a cool,
Handling and Storage:
dry, well-ventilated place.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form:dark gray solid
Molecular Weight:487.077
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:3.031
Odor:none
Solubility in Water:decomposes
SECTION 10: Stability and Reactivity
Stability:moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:prolonged exposure to moisture
Incompatibility:water, acids
Decomposition Products:cadmium oxide, arsenic oxide
SECTION 11: Toxicological Information
For Cd: Inhalation (human); TCLo: 8630 ug/m3/5H. Inhalation (Human-man); TCLo: 500 ug/m3/5Y-I.
Inhalation (Human-man); TCLo: 40 ug/m3. Oral (rat); LD50: 72 mg/kg. Intraperitoneal (rat); LD50: 12 mg/kg.
Intravenous (rat); LD50: 25 mg/kg. Oral (mouse); LD50: 72 mg/kg. Inhalation (mouse); LC50:250 mg/m3/2H.
Subcutaneous (mouse); LD50: 94 mg/kg. Inhalation (dog); LC50:4 gm/m3/10M. Oral (rat); TDLo: 156
ug/kg/26W-I. Inhalation (rat); TCLo: 23 ug/m3/24H/20W-C. Subcutaneous (rat); TDLo: 90 mg/kg. Oral (rat);
TDLo: 21640 ug/kg. Oral (rat); TDLo: 21640 ug/kg. For As: Oral (Human-man); LDLo: 29 mg/kg. Oral
RTECS Data:
(Human-man); LDLo: 286/mg/kg. Oral (Human-man); TDLo: 14857 ug/kg. Oral (Human); LDLo: 1429 ug/kg.
Oral (Human-man); LDLo: 2857 mg/kg. Oral (rat); LD50: 14600 ug/kg. Intraperitoneal (rat); LD50: 871 mg/kg.
Subcutaneous (rat); LDLo:8 mg/kg. Oral (mouse); LD50: 31500 ug/kg. Subcutaneous (mouse); LD50: 9800
ug/kg. Intravenous (mouse); LD50: 10700 ug/kg. Oral (dog); LDLo: 10 mg/kg. Intravenous (rabbit); LDLo:
10560 ug/kg. Oral (rat); TDLo: 900 mg/kg. Oral (rat); TDLo: 350 ug/kg/30D-I. Inhalation (rat); TCLo: 31
ug/m3/24H/22W-C. Inhalation (rat); TCLo: 500 ug/m3/24H/33D-C.
Carcinogenic Effects:Known carcinogens
Mutagenic Effects:As: mutagen
Tetratogenic Effects:Reproductive effectors
SECTION 12: Ecological Information
Avoid release into the environment. Very toxic to aquatic organisms. May cause long-term adverse effects in
Ecological Information:
the aquatic environment.
SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR):Cadmium compounds
Hazard Class (CFR):6.1
Additional Hazard Class (CFR):NA
Packaging Group (CFR):III
UN ID Number (CFR):UN# 2570
Shipping Name (IATA):Cadmium compound
Hazard Class (IATA):6.1
Additional Hazard Class (IATA):NA
Packaging Group (IATA):III
UN ID Number (IATA):UN# 2570
SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory
SARA (Title 313):See Category Codes N078 and N020 for reporting.
Second Ingredient:none
Tel: (978) 499 1600
Fax: (978) 465 3104
Toll free (in USA & Canada)
Tel: (800) 647 8736
Fax: (800) 517 8736
info@strem.com
Strem Chemicals, Inc.
15, rue de l'Atome, Z.I.
67800 BISCHHEIM (France)
Tel: (33) 03 88 62 52 60
Fax: (33) 03 88 62 26 81
info.europe@strem.com
Strem Chemicals, Inc.
Postfach 1215
77672 KEHL (Germany)
Telefon: 0 78 51/ 7 58 79
info.europe@strem.com
Strem Chemicals UK, Ltd.
Newton Hall
Town Street
Newton
Cambridge, England CB22 7ZE
Tel: 0845 643 7263
Fax: 0845 643 7362
enquiries@strem.co.uk
SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用

2、 摩尔体积（cm³/mol）： 无可用

3、 等张比容（90.2K）：无可用

4、 表面张力（dyne/cm）：无可用

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:5

8.表面电荷:0

9.复杂度:6.9

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3