bis(ethylcyclopentadienyl)manganese

物化性质

沸点：

~80ºC(lit.)

闪点：

230 °F

存储条件/存储方法：

密封储存，储存于阴凉、干燥的库房。远离热源，火花，火焰。常用氮气保护。

稳定性相关：

常温常压下稳定，避免与空气，水分，强氧化剂接触。

其它信息：

1. 性状：液体

2. 密度（g/mL,20℃）：未确定

3. 相对蒸汽密度（g/mL,空气=1）：未确定

4. 熔点（ºC）：未确定

5. 沸点（ºC,常压）：80

6. 沸点（ºC，1.5mmHg）：未确定

7. 折射率(n20/D)：未确定

8. 闪点（ºC）：110

9. 比旋光度（º）：未确定

10. 自燃点或引燃温度（ºC）：未确定

11. 蒸气压（mmHg,20ºC）：未确定

12. 饱和蒸气压（kPa,25ºC）：未确定

13. 燃烧热（KJ/mol）：未确定

14. 临界温度（ºC）：未确定

15. 临界压力（KPa）：未确定

16. 油水（辛醇/水）分配系数的对数值：未确定

17. 爆炸上限（%,V/V）：未确定

18. 爆炸下限（%,V/V）：未确定

19. 溶解性：未确定

安全信息

沸点：

~80ºC(lit.)

闪点：

230 °F

存储条件/存储方法：

密封储存，储存于阴凉、干燥的库房。远离热源，火花，火焰。常用氮气保护。

稳定性相关：

常温常压下稳定，避免与空气，水分，强氧化剂接触。

其它信息：

1. 性状：液体

2. 密度（g/mL,20℃）：未确定

3. 相对蒸汽密度（g/mL,空气=1）：未确定

4. 熔点（ºC）：未确定

5. 沸点（ºC,常压）：80

6. 沸点（ºC，1.5mmHg）：未确定

7. 折射率(n20/D)：未确定

8. 闪点（ºC）：110

9. 比旋光度（º）：未确定

10. 自燃点或引燃温度（ºC）：未确定

11. 蒸气压（mmHg,20ºC）：未确定

12. 饱和蒸气压（kPa,25ºC）：未确定

13. 燃烧热（KJ/mol）：未确定

14. 临界温度（ºC）：未确定

15. 临界压力（KPa）：未确定

16. 油水（辛醇/水）分配系数的对数值：未确定

17. 爆炸上限（%,V/V）：未确定

18. 爆炸下限（%,V/V）：未确定

19. 溶解性：未确定

MSDS

Section 1: Product Identification
Bis(ethylcyclopentadienyl)manganese, min. 98%, 25-0210, contained in 50 ml Swagelok® cylinder (96-1070)
Chemical Name:
for CVD/ALD
CAS Registry Number:101923-26-6
Formula:[(C2H5)C5H4]2Mn
EINECS Number:none
Chemical Family:metallocene
Synonym:none
Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound101923-26-6100%0.2mg/m3 (as Mn)5mg/m3 (as Mn-
Section 3: Hazards Identification
May be irritating to, skin, eyes and mucous membranes. May be harmful if swallowed. Some manganese
Emergency Overview:
compounds are known to affect the central nervous system. Possible risk of irreversible effects.
Primary Routes of Exposure:Inhalation and ingestion
Eye Contact:May cause slight to mild irritation of the eyes.
Skin Contact:May cause slight to mild irritation of the skin.
Vapor or mist may be irritating to the nose, mucous membranes and respiratory tract. May cause chronic
Inhalation:
health problems.
Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:May be irritaitng to the nose, mucous membranes and respiratory tract.
Prolonged exposure to manganese containing vapor or mist may produce manganese pneumonitis and
Chronic Health Affects:manganese poisoning. Symptoms include sleepiness, weakness and emotional disturbances. Equivocal
studies have shown manganese may decrease fertility in men. Possible risk of irreversible effects.
NTP:No
IARC:No
OSHA:No
SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire, this material may emit toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: Highly flammable. Formation of explosive air/dust mixtures is possible.
SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
Spill and Leak Procedures:
swept up.
SECTION 7: Handling and Storage
Handle and store the material under an inert atmosphere of nitrogen or argon. Keep in a cool, dry
Handling and Storage:
well-ventilated area. Prolongrd exposure to air or moisture will result in degradation of the product.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form:dark red liq.
Molecular Weight:241.23
Melting Point:not applicable
Boiling Point:no data
Vapor Pressure:0.1 torr @ 50-65°
Specific Gravity:no data
Odor:none
Solubility in Water:reacts with water
SECTION 10: Stability and Reactivity
Stability:air sensitive, moisture sensitive
Hazardous Polymerization:no hazardous polymerization
contact with moisture and oxygen. Keep away from heat and ignition sources including open flame and
Conditions to Avoid:
electostatic discharge.
Incompatibility:air, oxidizing agents, halogens, protoc agents
Decomposition Products:Carbon dioxide, carbon monoxide, organic fumes and manganese oxide.
SECTION 11: Toxicological Information
RTECS Data:No information available from the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:Possible mutagen (as Mn)
Tetratogenic Effects:no data
SECTION 12: Ecological Information
Ecological Information:No information available.
SECTION 13: Disposal Considerations
Disposal:Dispose of this material according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR):Flammable solids, Organic, N.O.S.
Hazard Class (CFR):4.1
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 1325
Shipping Name (IATA):Flammable solid, Organic, N.O.S.
Hazard Class (IATA):4.1
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 1325
SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):See Category code N450 for reporting
Second Ingredient:none
SECTION 16 - ADDITIONAL INFORMATION
N/A

分子结构与计算化学数据

分子结构数据

1、摩尔折射率：无可用的

2、摩尔体积（cm³/mol）：无可用的

3、等张比容（90.2K）：无可用的

4、表面张力（dyne/cm）：无可用的

5、介电常数：无可用的

6、极化率（10^-24cm³）：无可用的

7、单一同位素质量：241.0789 Da

8、标称质量：241 Da

9、平均质量：241.2308 Da

计算化学数据

1、 疏水参数计算参考值（XlogP）：

2、 氢键供体数量：0

3、 氢键受体数量：8

4、 可旋转化学键数量：2

5、 互变异构体数量：

6、 拓扑分子极性表面积（TPSA）：0

7、 重原子数量：15

8、 表面电荷：-8

9、 复杂度：250

10、同位素原子数量：0

11、确定原子立构中心数量：0

12、不确定原子立构中心数量：0

13、确定化学键立构中心数量：0

14、不确定化学键立构中心数量：0

15、共价键单元数量：3