5,9,14,18-Anthrazinetetrone,7,16-dichloro-6,15-dihydro-
- 中文别名：颜料蓝64
- 中文释义：颜料蓝64;士林漂蓝 BC;还原蓝 6;士林漂蓝BCS
- 英文别名：Vat Blue 6;
Dichloroindanthrone;
C Blue 9;
Vat Blue KD;
7,16-Dichloro-6,15-dihydro-5,9,14,18-anthrazinetetrone;
7,16-Dichlor-6,15-dihydro-dinaphtho[2,3-a,2',3'-h]phenazin-5,9,14,18-tetraon;
Blue BC;
7,16-dichloro-6,15-dihydro-dinaphtho[2,3-a,2',3'-h]phenazine-5,9,14,18-tetraone;
Vat Blue K;
Pigment Blue 64;
Blue K;
3,3'-dichloroindanthrone;
AO204;
C Blue No.9
- CAS No.：130-20-1
- 分子式：C28H12Cl2N2O4
- 分子量：511.31
- 精确分子量：510.01700
- PSA：99.86000
- InChI：InChI=1/C28H12Cl2N2O4/c29-17-9-15-19(27(35)13-7-3-1-5-11(13)25(15)33)23-21(17)32-24-20-16(10-18(30)22(24)31-23)26(34)12-6-2-4-8-14(12)28(20)36/h1-10,31-32H
- 分子结构式：
物化性质
- 密度：
- 1.591g/cm3
- 沸点：
- 788.5ºC at 760mmHg
- 闪点：
- 430.6ºC
- 折射率：
- 1.746
- 蒸汽压：
- 7.83E-25mmHg at 25°C
- 稳定性相关：
- 其它信息：
1.性状：蓝绿色粉末。
2.溶解性：不溶于水、丙酮、乙醇、甲苯，微溶于氯仿 (热)、邻氯苯酚、吡啶 (热)。于浓硫酸中呈棕色，稀释后呈蓝色。于保险粉碱性溶液中呈绿光蓝色，于酸性液中呈红光蓝色。
安全信息
- 密度：
- 1.591g/cm3
- 沸点：
- 788.5ºC at 760mmHg
- 闪点：
- 430.6ºC
- 折射率：
- 1.746
- 蒸汽压：
- 7.83E-25mmHg at 25°C
- 稳定性相关：
- 其它信息：
1.性状：蓝绿色粉末。
2.溶解性：不溶于水、丙酮、乙醇、甲苯，微溶于氯仿 (热)、邻氯苯酚、吡啶 (热)。于浓硫酸中呈棕色，稀释后呈蓝色。于保险粉碱性溶液中呈绿光蓝色，于酸性液中呈红光蓝色。
毒理性
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- CB8760000
- CHEMICAL NAME :
- 5,9,14,18-Anthrazinetetrone, 7,16-dichloro-6,15-dihydro-
- CAS REGISTRY NUMBER :
- 130-20-1
- BEILSTEIN REFERENCE NO. :
- 0068486
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 8
- MOLECULAR FORMULA :
- C28-H12-Cl2-N2-O4
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >10 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(6),85,1987
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 420 mg/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Behavioral - somnolence (general depressed activity) Behavioral - food intake (animal)
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(6),85,1987
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1800 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GNAMAP Gigiena Naselennykh Mest. Hygiene in Populated Places. (Izdatel'stvo Zdorov'ya, Kiev, USSR) V.7- 1967- Volume(issue)/page/year: 14,152,1975
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 25 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- GNAMAP Gigiena Naselennykh Mest. Hygiene in Populated Places. (Izdatel'stvo Zdorov'ya, Kiev, USSR) V.7- 1967- Volume(issue)/page/year: 14,152,1975 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 30 gm/kg/30D-I
- TOXIC EFFECTS :
- Kidney, Ureter, Bladder - proteinuria Kidney, Ureter, Bladder - other changes in urine composition Blood - changes in leukocyte (WBC) count
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 52(6),85,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X8842 No. of Facilities: 463 (estimated) No. of Industries: 8 No. of Occupations: 13 No. of Employees: 24086 (estimated) No. of Female Employees: 20898 (estimated)
MSDS
Material Safety Data Sheet
Section1. Identification of the substance
Product Name:Vat blue 6
Synonyms:
Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
Section3. Composition/information on ingredients.
Ingredient name:Vat blue 6
CAS number:130-20-1
Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.
Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.
Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.
Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Store in closed vessels.
Storage:
Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.
Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
No data
Melting point:
Flash point:No data
Density:No data
Molecular formula:C28H12Cl2N2O4
Molecular weight:511.3
Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, hydrogen chloride.
Section11. Toxicological information
No data.
Section12. Ecological information
No data.
Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.
Section14. Transportation information
Non-harzardous for air and ground transportation.
Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.
SECTION 16 - ADDITIONAL INFORMATION
N/A
海关数据
中国海关编码：2933990090
- 概述：
- 2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
- 申报要素：
- 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
- 摘要/Summary：
- 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
分子结构与计算化学数据
计算化学数据
1.疏水参数计算参考值（XlogP）:6.1
2.氢键供体数量:2
3.氢键受体数量:6
4.可旋转化学键数量:0
5.互变异构体数量:25
6.拓扑分子极性表面积92.3
7.重原子数量:36
8.表面电荷:0
9.复杂度:926
10.同位素原子数量:0
11.确定原子立构中心数量:0
12.不确定原子立构中心数量:0
13.确定化学键立构中心数量:0
14.不确定化学键立构中心数量:0
15.共价键单元数量:1
